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However, if one increases the content of transition metal salt only at constant concentration of organo-aluminum component then molecular masses do not change [ 1741. As a rule polymer products synthesized on Ziegler-Natta catalysts have broad MMD that is concerned with the presence of several AS types differing in kinetic activity [217-2231. The method of determining of AS distribution function by possibility of propagating chain limitation based on total MMD data analysis and do not considering suggestions about its form was proposed for the first time under ethylene polymerization on titanium-magnesium catalysts [217].

It is obvious that various electrophilic catalysts interesting for piperylene cationic oligomerization E2401 possess various activities. It determines principle possibility of improving of oligopiperylene industrial production as a base of synthetic drying oil production by selection of catalytic system with corresponding activity and selectivity. 0(C6H5)2, ~Z, Al(CzH5)2Cl and kinetic calculation of reaction zone (reactor) geometry are seemed to be expedient. 3. Ethylene and propylene copolymerization Ethylene-propylene rubbers are the important class of elastomers and are widely used in many branches of industry due to their unique properties, in particular good stability to environmental effects, good physical-chemical and elastic characteristics, chemical and ozone-stability, radiation, oils, acids and alkalis stability, etc.

Tic14 and SnC14 turned to be the most useful. Application of SbCl5 and InC13 doesn't provide acceptable polymerization rate, and in the case of AlC13 insoluble polymer was formed [246]. ) allows to produce oligopiperylene with high yield (80-95%) with desired MM (80-2000) at comparable high process duration (nearly 1 hour). Polymerization process in toluene medium is characterized by the first orders by catalyst and monomer with constants of chain propagation, transfer on monomer and catalyst rates 1,5, 0,04 and 0,86 Vmolemin accordingly.

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